Celogentin C and Thioviridamide
Author | : Dmitry Nikolayevich Litvinov |
Publisher | : |
Total Pages | : 142 |
Release | : 2010 |
ISBN-10 | : OCLC:730423470 |
ISBN-13 | : |
Rating | : 4/5 ( Downloads) |
Download or read book Celogentin C and Thioviridamide written by Dmitry Nikolayevich Litvinov and published by . This book was released on 2010 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Project III: Model studies towards the synthesis of the [beta]-thioenamide subunit of thioviridamide were performed. The radical addition reaction of thiyl radicals to ynamides produces Z- (kinetic products) or E- [beta]-thioenamides (thermodynamic products) depending on the reaction conditions. Two distinct sets of reaction conditions allowing kinetic or thermodynamic control of [beta]-thioenamide formation were developed. Synthesis of the model [beta]-thioenamide subunit of thioviridamide was attempted.