Synthesis and Reactivity of Organometallic Nitridoosmium (vi), Ruthenium (vi) Complexes

Download or read book Synthesis and Reactivity of Organometallic Nitridoosmium (vi), Ruthenium (vi) Complexes written by Naijie Zhang and published by . This book was released on 1991 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: New organometallic osmium(VI) complexes with sulfur and oxygen containing ligands, (Os(N)(CH$\sb2$SiMe$\sb3)\sb2$Y) $\sp-$ $\{$Y = (SCH$\sb2$CH$\sb2$S), (SCN)$\sb2$, (S), (S-C$\sb5$H$\sb4$N), (WS$\sb4$), (MoS$\sb4$), (SO$\sb4$), (CO$\sb3$), (ReO$\sb4)\sb2\}$ were prepared. Two crystal structures of (Os(N)(R)$\sb2$(SC$\sb5$H$\sb4$N)) $\sb2$, (NBu$\sp{\rm n}\sb4$) (Os(N)(R)$\sb2$(WS$\sb4$)) (R = CH$\sb2$SiMe$\sb3)$ were determined.