Binuclear Late Transition Metal Complexes with Pyrazole Based Compartmental Ligands

Download or read book Binuclear Late Transition Metal Complexes with Pyrazole Based Compartmental Ligands written by Michael Kojo Ainooson and published by . This book was released on 2014 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: A series of pyrazolate based ligands with 3,5-substituted side arms on the heterocycle have been established as valuable synthons for the preparation of highly compartmentalized bi- and oligonuclear metal complexes. Homo- and heterobimetallic late transition complexes with ligands that possess appended imine donor sidearms and two adjacent binding compartments akin to the [alpha]-diimine type ligands have been synthesized and fully characterized. Possible cooperative interactions between the metal centers in some selected organometallic transformation reactions have also been investigated ...