Hydrogen-bonded Supramolecular Materials for Organic Photovoltaic Applications

Download or read book Hydrogen-bonded Supramolecular Materials for Organic Photovoltaic Applications written by Cheng-Che Chu and published by . This book was released on 2009 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This research aims to elucidate the use of supramolecular interaction to guide the formation of well-defined nanoscale self-assembled architecture in photovoltaic solar cells as a means to improve device efficiency. Complementary molecular recognition sites based on melamine and barbituric acid were used to obtain functionalized fullerene and oligothiophene materials with superior processibility thanks to the presence of specific solubilizing groups. The efficiency of solid-state devices fabricated using the bulk heterojunction design was studied with respect to device morphology and composition. Experiments on recombination mechanism and field effect mobilities suggest that the balance between hydrogen-bonding interactions induce self-assembly and p-p interactions to promote phase segregation is crucial to the micro-structure of the active layer. The investigated of the relationship between the oligothiophene chain size and various complementary hydrogen-bonding motifs is envisaged.